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O CoA represents the rest of the coenzyme A molecule CoA S acetyl CoA OO better leaving group than alkoxide SEt a simple thiol ester O H OEt an ordinary ester OH SEt OH OEt SEt HO O faster HOO with thiol ester O OH SEt SEt tetrahedral intermediate: conjugation destroyed Another reaction that goes better with thiol esters than with ordinary esters is enolization.

Dhodhi, consider making a custom class that encapsulates all these details (and make sure it includes the Serializable attribute, as discussed in Chapter 6).

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